电化学研究所
邢丽丹  讲师      Email:xingld@scnu.edu.cn


锂离子电池电解质材料性质的理论与实验研究;储能器件电极/电解质界面设计和性质研究。



个人简介:

邢丽丹,女,博士。自2007 年以来,以“电化学储能材料与技术教育部工程研究中心”和“广东高校电化学储能与发电技术重点实验室”为研究平台,主要从事锂离子电池电极/电解液界面性质的研究工作,致力于提高电池电极/电解液界面稳定性的研究。掌握了锂离子电池的装配技术、电池性能测试以及电池材料表征等方法。在这6 年期间,以项目主要完成人参与了所在课题组的“嵌锂电极含硫界面膜的形成过程及其性质研究”(国家自然科学基金),“锂离子电池磷基芳环双齿配体结构锂盐的制备及其性质研究”(国家自然科学基金),“基于功能电解质的锂离子电池性能突破新材料开发”(广东省科技计划国际合作项目)和“安全低成本的锂离子电池功能电解质材料开发与应用”(广东省攻关重点项目)等项目的研究工作。其中,研究成果“锂离子电池凝胶聚合物隔膜及功能电解质的设计与制备技术”获得了2012 年度广东省科学技术奖一等奖,申请人是主要参与者之一。 于2010 年获得国家公派联合培养博士奖学金,到美国University of Utah大学的材料科学工程进行为期19 个月的学习。参与了Bedrova 教授课题组几个项目的研究,包括"Simulation of electrode- electrolyte interfaces in carbonate based and ionic liquid based Li-ion battery applications." General Motors,2010-2012,"Molecular simulation study of Li-ion batteries" Dept. of Energy, BATT Program,2008-2012 以及"SISGR: The influence of electrolyte structure and electrode morphology onthe performance of ionic-liquid based supercapacitors" Dept. of Energy, 2009-2012。掌握了应用分子动力学模拟方法和量子化学计算方法研究锂离子电池以及超级电容器的电极/电解液界面结构及溶剂分解反应激励研究的方法。 讲授课程包括《应用电化学》和《新型电池材料》。



教育背景:

200309-200707   华南师范大学    化学与环境学院 学士

200709-201207   华南师范大学    化学与环境学院  推免硕博连读 博士

201010-201203  University of Utah  国家公派联合培养博士
 


获奖与荣誉:

[1] 李伟善,廖友好,许梦清,梁 英,刘建生,李 斌,张若昕,饶睦敏,李小平,邢丽丹,周代营,谭春林,傅昭,张利萍,冯岸柏,锂离子电池凝胶聚合物隔膜及功能电解质的设计与制备技术,广东省教育厅,广东省科学技术奖,一等奖,2012 年。


主要论文:

[1] Lidan XingJenel Vatamanu, Oleg Borodin, Dmitry Bedrova, On the Atomistic Nature of Capacitance Enhancement Generated by Ionic Liquid Electrolyte Confined in Subnanometer Pores[J]. J. Phys. Chem. Lett. 4: 132-140, 2013. 

[2] Lidan XingJenel Vatamanu, Dmitry Bedrova, Grant D Smith, Nanopatterning of electrode surfaces as a route to improved energy storage in electrostatic capacitors[J]. J. Phys. Chem. Lett. 3: 1124-1129, 2012. 

[3] Lidan Xing, Jenel Vatamanu, Dmitry Bedrova, Oleg Borodin, Grant D Smith, Electrode/ Electrolyte Interface in Sulfolane-Based Electrolytes for Li Ion Batteries: A Molecular Dynamics Simulation Study[J]. J. Phys. Chem. C. 116:23871-23881, 2012. 

[4] Lidan XingOleg Borodin, Oxidation induced decomposition of ethylene carbonate from DFT calculations - importance of explicitly treating surrounding solvent [J]. Phys. Chem. Chem. Phys. 14:12838-12843, 2012. 

[5] Lidan Xing, Weishan Li, Mengqing Xu, Tiantian Li, Liu Zhou, The reductive mechanism of ethylene sulfite as solid electrolyte interface film forming additive for lithium ion battery[J]. J. Power Sources,196: 7044-7047, 2011. 

[6] Lidan XingOleg Borodin, Grant Smith, Weishan, Li, A Density Function Theory Study of the Role of Anions on the Oxidative Decomposition Reaction of Propylene Carbonate[J] J. Phys. Chem. A. 115: 13896-13905, 2011. 

[7] Lidan Xing, Chaoyang Wang, Weishan Li, Mengqing Xu, Xuliang Meng, Shaofei Zhao, Theoretical insight into oxidative decomposition of propylene carbonate in the lithium ion battery[J]. J. Phys. Chem. B. 113(15):5181-5187, 2009. 

[8] Lidan Xing, Chaoyang Wang, Mengqing Xu, Weishan Li, Zongping Cai, Theoretical study on reduction mechanism of 1,3-benzodioxol-2-one for the formation of solid electrolyte interface on anode of lithium ion battery[J]. J. Power Sources, 189: 689-692, 2009. 

[9] Lidan Xing, Weishan Li, Chaoyang Wang, Mengqing Xu, Chunlin Tan, Jin Yi, Theoretical investigations on oxidative stability of solvents and oxidative decomposition mechanism of ethylene carbonate for lithium-ion battery use. [J] J. Phys. Chem. B. 113(52):16596-16602, 2009. 

[10] Tiantian Li, Lidan Xing, Weishan Li, Yating Wang, Mengqing Xu, Fenglong Gu, Shejun Hu, How does lithium salt anion affect oxidation decomposition reaction of ethylene carbonate: A density functional theory study[J], J. Power Sources, in press, 2013

[11] Tiantian Li, CaoYang Wang, Lidan Xing, Weishan Li, Bin Peng, Mengqing Xu, Fenglong Gu, Shejun Hu, Reaction Mechanism of 1,4-Dimethoxy Benzene as an Overcharge Protection Additive, Acta Phys.-Chim. Sin. 28: 818-822, 2012. 

[12] Tiantian Li, Lidan Xing, Weishan Li, Bin Peng, Mengqing Xu, Fenglong Gu, Shejun Hu, Theoretic calculation for understanding oxidation process of 1,4-dimethoxy benzene based compounds as redox shuttles for overcharge protection of lithium ion battery, J. Phys. Chem. A,

115: 4988-4994, 2011. 

[13] Mengqing Xu, Liu Zhou, Lianshen Hao, Lidan Xing, Weishan Li, Brett Lucht, Investigation and Application of Lithium Difluoro(oxalate)borate (LiDFOB) as Additive to Improve the Thermal Stability of Electrolyte for Lithium Ion Batteries, J. Power Sources, 169:6794-6801, 2011. 

[14] Mengqing Xu, Lianshen Hao, Yanlin Liu, Lidan Xing, Weishan Li, Bin Li, Experimental and Theoretical Investigations of Dimethyl Acetamide (DMAc) as Electrolyte Stabilizing Additive for Lithium Ion Batteries, J. Phys. Chem. C. 115:6085-6094, 2011. 

[15] Mengqing Xu, Liu Zhou, Lidan Xing, Weishan Li, Brett Lucht, Experimental and Theoretical Investigations on 4,5-Dimethyl-[1,3] dioxol-2-one as Solid Electrolyte Interface Forming Additive for Lithium-ion Batteries, Electrochim. Acta, 55:6743-6748, 2010. 

[16] Lu Yue, Weishan Li, Lingzhi Zhao, Lidan Xing, Fengqiang Sun, Highly hydroxylated carbon fibres as electrode materials of all-vanadium redox flow battery, Carbon, 48: 3079-3090, 2010. 

[17] Zongping Cai, Ying Liang, Weishan Li, Lidan Xing, Youhao Liao, Preparation and performances of LiFePO4 cathode in aqueous solvent with polyacrylic acid as a binder, J. Power Sources, 189:547-551, 2009. 


主要专利:

[1] 许梦清,邢丽丹,李伟善,发明专利,“用于高电压锂离子电池的非水电解液及其制备方法与应用,”申请号:200910193637.6

[2] 许梦清,邢丽丹,李伟善,发明专利,“锂离子电池用的非水电解液及其制备方法与应用,”申请号:200910193635.7

[3] 许梦清,邢丽丹,李伟善,发明专利,“用于锂离子电池的阻燃电解液及其制备方法与应用,”申请号:200910193634.2,专利号: ZL 200910193634.2,授权日期:2011.12.14

[4] 廖友好,饶睦敏,邢丽丹,李伟善,陈朗,发明专利,“一种凝胶态聚合物锂离子电池电解质及其制备方法和应用,”申请号:200910040464.4,专利号:ZL 200910040464.4

[5] 蔡宗平,李伟善,邢丽丹,廖友好,郝连升,发明专利,“改善电极电解液界面相容性的锂离子电池电极及其制备方法与应用,”申请号:200910038208.1


邀请报告:

参加国际会议情况:

[1] Lidan Xing, et al. Theoretical study on reduction mechanism of 1,3-benzodioxol-2-one for the formation of solid electrolyte interface on anode of lithium ion battery,The 14th International Meeting on Lithium Batteries IMLB, Tianjin, 2008, poster.

[2] Lidan Xing, et al. Influence of Anion on Propylene Carbonate Oxidative Decomposition Pathways from DFT Calculations, 220th ECS Meeting, Boston, MA. 2011, poster.

[3] Lidan Xing(报告人), et al. Improving the Energy Density of Electric Double Layer Capacitors by Nanopatterning the Electrode Surface: Insights from Simulation, 1st International Conference on Emerging Advanced Nanomaterials (ICEAN), Brisbane, Australia, 2012, invited presentation.


主要著作:

[1] Mengqing Xu, Lidan Xing, Weishan Li, “Electrolytes and Anode Interfacial Chemistry”, Springer, 2013, in press.





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华南师范大学 化学与环境学院  地址:广州大学城外环西路 邮政编码:510006 道德自查