Improving Electrochemical Stability and Low-Temperature Performance with Water/Acetonitrile Hybrid Electrolytes
作者: Chen, JW (Chen, Jiawei); Vatamanu, J (Vatamanu, Jenel); Xing, LD (Xing, Lidan); Borodin, O (Borodin, Oleg); Chen, HY (Chen, Huiyang); Guan, XC (Guan, Xiongcong); Liu, X (Liu, Xiang); Xu, K (Xu, Kang); Li, WS (Li, Weishan)
标题: Improving Electrochemical Stability and Low-Temperature Performance with Water/Acetonitrile Hybrid Electrolytes
来源出版物: ADVANCED ENERGY MATERIALS
卷: 10
期: 3
文献号: 1902654
DOI: 10.1002/aenm.201902654
提前访问日期: NOV 2019
出版年: JAN 2020
摘要: Although the "water-in-salt" electrolyte has significantly expanded the electrochemical stability window of aqueous electrolytes from 1.23 to 3 V, its inevitable hydrogen evolution under 1.9 V versus Li+/Li prevents the practical use of many energy-dense anodes. Meanwhile, its liquidus temperature at 17 degrees C restricts its application below ambient temperatures. An advanced hybrid electrolyte is proposed in this work by introducing acetonitrile (AN) as co-solvent, which minimizes the presence of interfacial water at the negatively charged electrode surface, and generates a thin and uniform interphase consisting of an organic outer layer based on nitrile (C(sic)N) and sulfamide (R-S-N-S) species and an inner layer rich in LiF. Such an interphase significantly suppresses water reduction and expands the electrochemical stability window to an unprecedented width of 4.5 V. Thanks to the low freezing point (-48 degrees C) and low viscosity of AN, the hybrid electrolyte is highly conductive in a wide temperature range, and enables a LiMn2O4/Li4Ti5O12 full cell at both ambient and sub-ambient temperatures with excellent cycling stability and rate capability. Meanwhile, such a hybrid electrolyte also inherits the nonflammable nature of aqueous electrolyte. The well-balanced merits of the developed electrolyte make it suitable for high energy density aqueous batteries.
关键词
作者关键词: acetonitrile; aqueous lithium-ion batteries; aqueous; nonaqueous hybrid electrolytes; electrochemical stabilities; low-temperature performance
KeyWords Plus: PHASE-DIAGRAM; LITHIUM; SAFE; BATTERIES